PhyslibAlpha.QuantumMechanics.OperatorAlgebra.States.Statistics
State statistics
A state assigns real expectation values to observables. Centering observables produces covariance and variance, the quantities used in uncertainty relations.
Expectation
Centering
Covariance and variance
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Expectation value of an observable in state
Given a state on a -algebra , the expectation value is an -linear map from the space of observables to the real numbers . For an observable (a self-adjoint element such that ), the expectation value is defined as the real part of the value obtained by applying the positive linear map associated with to . Physically, this represents the mean value or average of repeated measurements of the observable on a system prepared in state .
Notation for expectation value of observable in state
Given a state and an observable in an operator algebra, the notation represents the expectation value of the observable with respect to the state .
for observables
Let be a -algebra, be a state on , and be an observable (a self-adjoint element such that ). The value of the complex-valued state functional applied to is equal to the real-valued expectation value of the observable , when the latter is treated as a complex number.
for the identity observable
Let be a unital -algebra and be a state on . The expectation value of the identity observable in the state , denoted by , is equal to .
Let be a unital -algebra. For any state on and any observable (a self-adjoint element), if is a positive element (denoted ), then the expectation value of in the state , denoted by , is non-negative: .
Centered observable
For a state on a -algebra and an observable , the centered observable is defined as , where is the expectation value of in the state and is the identity element of . This represents the fluctuation of the observable around its mean value, ensuring that the expectation value of the resulting centered observable is zero.
Let be a unital -algebra. For any state on and any observable , the expectation value of the centered observable (the fluctuation ) is zero: where denotes the expectation value of in state and is the identity element of .
Let be a state on a -algebra and be an observable (a self-adjoint element). For any real number , the centered observable of shifted by a constant is equal to the centered observable of : where denotes the fluctuation of the observable around its expectation value , and is the identity element of the algebra.
Covariance of observables and in state
For a state on a -algebra and two observables , the covariance is the expectation value of the Jordan product of the centered observables: where is the expectation value of , is the identity element, and is the Jordan product. This quantity represents the correlation between the fluctuations of the two observables in the state .
Variance of observable in state
For a state on a -algebra and an observable , the variance is defined as the covariance of the observable with itself: where is the expectation value of in the state and is the identity element of the algebra. This quantity represents the spread of the measurement outcomes of about its mean, serving as the quantum analogue of the variance of a random variable.
Let be a unital -algebra. For any state on and any observable , the covariance of with itself is equal to the variance of :
Let be a unital complex -algebra, be a state on , and be an observable (a self-adjoint element). The variance of in the state , denoted , is equal to the real part of the expectation value of the square of the centered observable: where is the centered observable representing the fluctuation of about its mean , and is the identity element of the algebra.
Symmetry of Covariance:
Let be a unital complex -algebra. For any state on and any two observables , the covariance between and in the state is symmetric, satisfying .
Covariance is invariant under shifting the first observable by a constant
Let be a unital -algebra and be a state on . For any two observables (self-adjoint elements) and any real number , the covariance of the shifted observable and is equal to the covariance of and : where denotes the identity element of the algebra. This reflects the property that covariance depends only on the fluctuations of the observables, and is therefore invariant under translations by a constant.
For a state on a -algebra and any two observables , shifting the second observable by a constant leaves the covariance unchanged: where is the identity element of . This property demonstrates that covariance depends only on the fluctuations of the observables, and adding a constant value to an observable does not affect its correlation with others.
Let be a unital complex -algebra, be a state on (a positive linear functional with unit norm), and be an observable (a self-adjoint element). The variance of in the state , denoted as , is always non-negative: This result states that the spread of repeated measurements of an observable about its mean can never be negative, which ensures that variance is a physically valid measure of statistical uncertainty. Algebraically, this follows from the positivity of the state applied to the square of the centered observable .
