Physlib

Physlib.QuantumMechanics.QuantumSystem.Basic

Quantum system

i. Overview

In non-relativistic quantum mechanics a quantum system is characterized by a Hilbert space (complete inner product space) and self-adjoint Hamiltonian operator; these data are collected in the `QuantumSystem` structure.

Two quantum systems are said to be "unitary equivalent" if there is a unitary bijection between their respective Hilbert spaces which sends one Hamiltonian to the other under conjugation. Unitary equivalent quantum systems are physically indestinguishable, as all operators, states, matrix elements, probabilities, eigenvalues, etc. are in 1-1 correspondence.

ii. Key results

Definitions - `QuantumSystem` : Structure bundling together a choice of Hilbert space and self-adjoint Hamiltonian operator. - `UnitaryRelation` : The unitary equivalence relation.

iii. Table of contents

  • A. Definition
  • B. Creation from an essentially self-adjoint operator
  • C. Zero
  • D. Unitary equivalence

iv. References

A. Definition

B. Creation from an essentially self-adjoint operator

An essentially self-adjoint operator has a unique self-adjoint extension (c.f. `IsEssentiallySelfAdjoint.unique_self_adjoint_extension`). For this reason, a quantum system can be uniquely associated to an e.s.a. Hamiltonian operator.

C. Zero

D. Unitary equivalence

11 declarations

instance

The Hilbert space HQ\mathcal{H}_Q is a normed additive commutative group.

For any quantum system QQ, the underlying Hilbert space HQ\mathcal{H}_Q is equipped with the structure of a normed additive commutative group.

instance

The Hilbert space HQ\mathcal{H}_Q is a complex inner product space

For any quantum system QQ, the underlying Hilbert space HQ\mathcal{H}_Q is equipped with the structure of an inner product space over the complex numbers C\mathbb{C}.

instance

The Hilbert space HQ\mathcal{H}_Q is a complete space

For any quantum system QQ, the underlying Hilbert space HQ\mathcal{H}_Q is a complete space.

definition

Quantum system from an essentially self-adjoint operator H\mathcal{H}

Let HSHS be a complex Hilbert space and H\mathcal{H} be a partially defined linear operator on HSHS (of type `LinearPMap`) that is essentially self-adjoint. This definition constructs a `QuantumSystem` by taking HSHS as the underlying Hilbert space and the closure H\overline{\mathcal{H}} as the self-adjoint Hamiltonian operator.

instance

The zero quantum system

The zero quantum system is defined as the system consisting of the zero-dimensional complex Hilbert space C0\mathbb{C}^0 and the zero operator 00 as its Hamiltonian.

definition

Unitary equivalence of Q1Q_1 and Q2Q_2

Two quantum systems Q1Q_1 and Q2Q_2 satisfy the unitary equivalence relation if there exists a unitary operator (expressed as a complex linear isometry equivalence) e:H1H2e: \mathcal{H}_1 \to \mathcal{H}_2 between their respective Hilbert spaces such that the domain of the Hamiltonian H1H_1 is mapped by ee onto the domain of the Hamiltonian H2H_2, and for every vector ψ\psi in the domain of H1H_1, the condition e(H1ψ)=H2(eψ)e(H_1 \psi) = H_2(e \psi) holds.

theorem

Unitary Equivalence of Quantum Systems is Reflexive

For any quantum system QQ, the relation of unitary equivalence is reflexive; that is, QQ is unitarily equivalent to itself.

theorem

Unitary equivalence of quantum systems is symmetric

For any two quantum systems Q1Q_1 and Q2Q_2, if Q1Q_1 is unitarily equivalent to Q2Q_2, then Q2Q_2 is unitarily equivalent to Q1Q_1. Here, unitary equivalence signifies that there exists a unitary operator between the respective Hilbert spaces that preserves the domain and action of the Hamiltonian operators.

theorem

Transitivity of Unitary Equivalence for Quantum Systems

Let Q1,Q2,Q_1, Q_2, and Q3Q_3 be quantum systems. If Q1Q_1 is unitarily equivalent to Q2Q_2 and Q2Q_2 is unitarily equivalent to Q3Q_3, then Q1Q_1 and Q3Q_3 are also unitarily equivalent.

theorem

Unitary equivalence is an equivalence relation

The unitary equivalence relation between quantum systems is an equivalence relation. This means the relation is reflexive, symmetric, and transitive.

instance

Setoid of quantum systems under unitary equivalence

This definition establishes a setoid structure on the collection of all quantum systems. A setoid is a type equipped with an equivalence relation; here, the equivalence relation is defined as the unitary equivalence between quantum systems Q1Q_1 and Q2Q_2. Two quantum systems are equivalent if there exists a unitary transformation between their respective Hilbert spaces that intertwines their Hamiltonian operators.