Physlib.QuantumMechanics.QuantumSystem.Basic
Quantum system
i. Overview
In non-relativistic quantum mechanics a quantum system is characterized by a Hilbert space (complete inner product space) and self-adjoint Hamiltonian operator; these data are collected in the `QuantumSystem` structure.
Two quantum systems are said to be "unitary equivalent" if there is a unitary bijection between their respective Hilbert spaces which sends one Hamiltonian to the other under conjugation. Unitary equivalent quantum systems are physically indestinguishable, as all operators, states, matrix elements, probabilities, eigenvalues, etc. are in 1-1 correspondence.
ii. Key results
Definitions - `QuantumSystem` : Structure bundling together a choice of Hilbert space and self-adjoint Hamiltonian operator. - `UnitaryRelation` : The unitary equivalence relation.
iii. Table of contents
- A. Definition
- B. Creation from an essentially self-adjoint operator
- C. Zero
- D. Unitary equivalence
iv. References
A. Definition
B. Creation from an essentially self-adjoint operator
An essentially self-adjoint operator has a unique self-adjoint extension (c.f. `IsEssentiallySelfAdjoint.unique_self_adjoint_extension`). For this reason, a quantum system can be uniquely associated to an e.s.a. Hamiltonian operator.
C. Zero
D. Unitary equivalence
11 declarations
The Hilbert space is a normed additive commutative group.
For any quantum system , the underlying Hilbert space is equipped with the structure of a normed additive commutative group.
The Hilbert space is a complex inner product space
For any quantum system , the underlying Hilbert space is equipped with the structure of an inner product space over the complex numbers .
The Hilbert space is a complete space
For any quantum system , the underlying Hilbert space is a complete space.
Quantum system from an essentially self-adjoint operator
Let be a complex Hilbert space and be a partially defined linear operator on (of type `LinearPMap`) that is essentially self-adjoint. This definition constructs a `QuantumSystem` by taking as the underlying Hilbert space and the closure as the self-adjoint Hamiltonian operator.
The zero quantum system
The zero quantum system is defined as the system consisting of the zero-dimensional complex Hilbert space and the zero operator as its Hamiltonian.
Unitary equivalence of and
Two quantum systems and satisfy the unitary equivalence relation if there exists a unitary operator (expressed as a complex linear isometry equivalence) between their respective Hilbert spaces such that the domain of the Hamiltonian is mapped by onto the domain of the Hamiltonian , and for every vector in the domain of , the condition holds.
Unitary Equivalence of Quantum Systems is Reflexive
For any quantum system , the relation of unitary equivalence is reflexive; that is, is unitarily equivalent to itself.
Unitary equivalence of quantum systems is symmetric
For any two quantum systems and , if is unitarily equivalent to , then is unitarily equivalent to . Here, unitary equivalence signifies that there exists a unitary operator between the respective Hilbert spaces that preserves the domain and action of the Hamiltonian operators.
Transitivity of Unitary Equivalence for Quantum Systems
Let and be quantum systems. If is unitarily equivalent to and is unitarily equivalent to , then and are also unitarily equivalent.
Unitary equivalence is an equivalence relation
The unitary equivalence relation between quantum systems is an equivalence relation. This means the relation is reflexive, symmetric, and transitive.
Setoid of quantum systems under unitary equivalence
This definition establishes a setoid structure on the collection of all quantum systems. A setoid is a type equipped with an equivalence relation; here, the equivalence relation is defined as the unitary equivalence between quantum systems and . Two quantum systems are equivalent if there exists a unitary transformation between their respective Hilbert spaces that intertwines their Hamiltonian operators.
