Physlib

Physlib.QuantumMechanics.Operators.Momentum

Momentum operators

i. Overview

In this module we introduce several momentum operators for quantum mechanics on `Space d`.

ii. Key results

Definitions: - `momentumCLM` : (components of) the momentum vector operator acting on Schwartz maps `𝓢(Space d, ℂ)` as `-iℏ∂ᵢ`. - `momentumOperator` : a symmetric unbounded operator acting on the Schwartz submodule of the Hilbert space `SpaceDHilbertSpace d`.

Notation: - `𝐩` for `momentumOperator`

iii. Table of contents

  • A. Momentum vector operator
  • B. Unbounded momentum vector operator

iv. References

A. Momentum vector operator

B. Unbounded momentum vector operator

8 declarations

definition

jj-th component of the momentum operator p^j\hat{p}_j as a continuous linear map

For a given dimension dd and an index j{0,1,,d1}j \in \{0, 1, \dots, d-1\}, this defines the jj-th component of the momentum operator p^j\hat{p}_j as a continuous linear map on the Schwartz space S(Space d,C)\mathcal{S}(\text{Space } d, \mathbb{C}). The operator acts on a Schwartz function ψ\psi by taking its partial derivative with respect to the jj-th coordinate of the standard basis, multiplied by i-i\hbar, where \hbar is the reduced Planck constant: p^jψ=iψxj \hat{p}_j \psi = -i\hbar \frac{\partial \psi}{\partial x_j}

theorem

Action of the ii-th momentum operator component piψ=iiψ\mathbf{p}_i \psi = -i\hbar \partial_i \psi

For any dimension dNd \in \mathbb{N} and coordinate index i{0,,d1}i \in \{0, \dots, d-1\}, let ψ:Space dC\psi: \text{Space } d \to \mathbb{C} be a Schwartz function. The ii-th component of the momentum operator pi\mathbf{p}_i applied to ψ\psi is given by: (piψ)=iiψ (\mathbf{p}_i \psi) = -i\hbar \partial_i \psi where ii is the imaginary unit, \hbar is the reduced Planck's constant, and i\partial_i denotes the partial derivative with respect to the ii-th coordinate.

theorem

The momentum operator pi\mathbf{p}_i equals ii-i\hbar \partial_i

For any dimension dd, coordinate index i{0,,d1}i \in \{0, \dots, d-1\}, Schwartz function ψ:Space dC\psi: \text{Space } d \to \mathbb{C}, and point xSpace dx \in \text{Space } d, the ii-th component of the momentum operator pi\mathbf{p}_i applied to ψ\psi and evaluated at xx is given by: (piψ)(x)=iψxi(x) (\mathbf{p}_i \psi)(x) = -i \hbar \frac{\partial \psi}{\partial x_i}(x) where ii is the imaginary unit, \hbar is the reduced Planck's constant, and ψxi\frac{\partial \psi}{\partial x_i} denotes the partial derivative of ψ\psi in the ii-th spatial direction.

definition

Notation for the momentum operator p\mathbf{p}

This definition introduces the mathematical notation p\mathbf{p} used to represent the momentum operator in quantum mechanics. The operator p\mathbf{p} acts on the space of Schwartz functions S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) such that its ii-th component is given by ixi-i\hbar\frac{\partial}{\partial x_i}.

theorem

Unbounded momentum operator Pi\mathbf{P}_i equals pi\mathbf{p}_i almost everywhere on the Schwartz submodule

Let Space d\text{Space } d be a dd-dimensional real inner product space. Let pi:S(Space d,C)S(Space d,C)\mathbf{p}_i: \mathcal{S}(\text{Space } d, \mathbb{C}) \to \mathcal{S}(\text{Space } d, \mathbb{C}) be the ii-th component of the momentum operator (defined as ii-i\hbar\partial_i on Schwartz functions). Let Pi\mathbf{P}_i be the corresponding ii-th component of the unbounded momentum operator acting on the Schwartz submodule of the Hilbert space L2(Space d,C)L^2(\text{Space } d, \mathbb{C}). For any ψ\psi in this Schwartz submodule, the application of Pi\mathbf{P}_i to ψ\psi is equal almost everywhere to the application of pi\mathbf{p}_i to the corresponding Schwartz function ψS=schwartzEquiv1(ψ)\psi_S = \text{schwartzEquiv}^{-1}(\psi). That is, Piψ=piψS \mathbf{P}_i \psi = \mathbf{p}_i \psi_S holds almost everywhere with respect to the volume measure on Space d\text{Space } d.

theorem

The momentum operator pip_i preserves the Schwartz space.

For any dimension dd and any index i{0,,d1}i \in \{0, \dots, d-1\}, if ψ\psi is a function in the Schwartz submodule S(Space d,C)\mathcal{S}(\text{Space } d, \mathbb{C}) of the Hilbert space L2(Space d,C)L^2(\text{Space } d, \mathbb{C}), then the result of applying the ii-th component of the momentum operator pi=iip_i = -i\hbar\partial_i to ψ\psi is also an element of the Schwartz submodule.

theorem

The momentum operator pip_i has a dense domain

For any dimension dNd \in \mathbb{N} and coordinate index ii, the ii-th component of the momentum operator pi=iip_i = -i \hbar \partial_i, which maps between Schwartz functions S(Space d,C)\mathcal{S}(\text{Space } d, \mathbb{C}), has a dense domain in the Hilbert space L2(Space d,C)L^2(\text{Space } d, \mathbb{C}). Here, \hbar is the reduced Planck constant and i\partial_i is the partial derivative with respect to the ii-th basis vector.

theorem

The Momentum Operator p^i\hat{p}_i is Symmetric

For any dimension dNd \in \mathbb{N} and any coordinate index i{0,,d1}i \in \{0, \dots, d-1\}, the ii-th component of the momentum operator p^i=ii\hat{p}_i = -i \hbar \partial_i, acting on the Schwartz space S(Space d,C)\mathcal{S}(\text{Space } d, \mathbb{C}), is a symmetric operator. This means that for all functions ψ,ϕS(Space d,C)\psi, \phi \in \mathcal{S}(\text{Space } d, \mathbb{C}), the L2L^2 inner product satisfies ψ,p^iϕ=p^iψ,ϕ\langle \psi, \hat{p}_i \phi \rangle = \langle \hat{p}_i \psi, \phi \rangle.