Physlib

Physlib.QuantumMechanics.Operators.AngularMomentum

Angular momentum operator

i. Overview

In this module we introduce several angular momentum operators for quantum mechanics on `Space d`.

ii. Key results

Definitions: - `angularMomentumOperator` : (components of) the angular momentum operator acting on Schwartz maps `𝓢(Space d, ℂ)` as `𝐱ᵢ∘𝐩ⱼ - 𝐱ⱼ∘𝐩ᵢ`. - `angularMomentumOperatorSqr` : the operator acting on Schwartz maps `𝓢(Space d, ℂ)` as `½ ∑ᵢⱼ 𝐋ᵢⱼ∘𝐋ᵢⱼ`. - `angularMomentumOperator2D` : the (pseudo)scalar angular momentum operator for `d = 2`. - `angularMomentumOperator3D` : the (pseudo)vector angular momentum operator for `d = 3`.

Notation: - `𝐋` for `angularMomentumOperator` - `𝐋²` for `angularMomentumOperatorSqr`

iii. Table of contents

- A. Angular momentum operator - A.1 Antisymmetry - B. Angular momentum squared operator - C. Special cases in low dimensions

iv. References

A. Angular momentum operator

A.1 Antisymmetry

B. Angular momentum squared operator

C. Special cases in low dimensions

• d = 1 : The angular momentum operator is trivial.

• d = 2 : The angular momentum operator has only one independent component, 𝐋₀₁, which may be thought of as a (pseudo)scalar operator.

• d = 3 : The angular momentum operator has three independent components, 𝐋₀₁, 𝐋₁₂ and 𝐋₂₀. Dualizing using the Levi-Civita symbol produces the familiar (pseudo)vector angular momentum operator with components 𝐋₀ = 𝐋₁₂, 𝐋₁ = 𝐋₂₀ and 𝐋₂ = 𝐋₀₁.

27 declarations · 1 submodule

Submodules

Declarations

definition

Angular momentum operator Lij=x^ip^j−x^jp^iL_{ij} = \hat{x}_i \hat{p}_j - \hat{x}_j \hat{p}_i

For a given dimension dd and indices i,j∈{0,1,…,d−1}i, j \in \{0, 1, \dots, d-1\}, the ijij-th component of the angular momentum operator LijL_{ij} is the continuous linear map from the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) to itself defined by the relation: Lij=x^ip^j−x^jp^i L_{ij} = \hat{x}_i \hat{p}_j - \hat{x}_j \hat{p}_i where x^i\hat{x}_i is the ii-th position operator (multiplication by the ii-th coordinate) and p^j\hat{p}_j is the jj-th momentum operator (acting as −iℏ∂j-i\hbar \partial_j on the Schwartz space).

definition

Notation for the angular momentum operator Lij\mathbf{L}_{ij}

The definition `QuantumMechanics.term𝐋` provides the notation for the angular momentum operator components Lij\mathbf{L}_{ij}. In quantum mechanics, these components are defined as Lij=xipj−xjpi\mathbf{L}_{ij} = \mathbf{x}_i \mathbf{p}_j - \mathbf{x}_j \mathbf{p}_i, where xi\mathbf{x}_i is the ii-th position operator and pj\mathbf{p}_j is the jj-th momentum operator acting on the space of Schwartz functions S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}).

definition

Notation for angular momentum operator components L[i,j]\mathbf{L}[i, j]

This definition introduces the notation L[i,j]\mathbf{L}[i, j] for the (i,j)(i, j)-th component of the angular momentum operator. It corresponds to the operator defined by L^ij=xip^j−xjp^i\hat{L}_{ij} = x_i \hat{p}_j - x_j \hat{p}_i acting on the space of Schwartz functions S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}), where xix_i is the position operator and p^j\hat{p}_j is the momentum operator.

theorem

Lijψ=x^ip^jψ−x^jp^iψ\mathbf{L}_{ij} \psi = \hat{x}_i \hat{p}_j \psi - \hat{x}_j \hat{p}_i \psi

For a dimension d∈Nd \in \mathbb{N} and indices i,j∈{0,1,…,d−1}i, j \in \{0, 1, \dots, d-1\}, let ψ∈S(Rd,C)\psi \in \mathcal{S}(\mathbb{R}^d, \mathbb{C}) be a Schwartz function. The (i,j)(i, j)-th component of the angular momentum operator Lij\mathbf{L}_{ij} applied to ψ\psi is given by: Lijψ=x^i(p^jψ)−x^j(p^iψ)\mathbf{L}_{ij} \psi = \hat{x}_i (\hat{p}_j \psi) - \hat{x}_j (\hat{p}_i \psi) where x^k\hat{x}_k and p^k\hat{p}_k denote the kk-th component of the position and momentum operators, respectively.

theorem

Pointwise application of LijL_{ij}: (Lijψ)(x)=(x^ip^jψ)(x)−(x^jp^iψ)(x)(L_{ij} \psi)(x) = (\hat{x}_i \hat{p}_j \psi)(x) - (\hat{x}_j \hat{p}_i \psi)(x)

For any dimension d∈Nd \in \mathbb{N} and indices i,j∈{0,1,…,d−1}i, j \in \{0, 1, \dots, d-1\}, let LijL_{ij} be the component of the angular momentum operator, x^k\hat{x}_k be the kk-th position operator, and p^k\hat{p}_k be the kk-th momentum operator acting on the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}). For any Schwartz function ψ\psi and any point x∈Rdx \in \mathbb{R}^d, the value of the function LijψL_{ij} \psi at xx is given by: (Lijψ)(x)=(x^i(p^jψ))(x)−(x^j(p^iψ))(x) (L_{ij} \psi)(x) = (\hat{x}_i (\hat{p}_j \psi))(x) - (\hat{x}_j (\hat{p}_i \psi))(x) where (x^kϕ)(x)=xkϕ(x)(\hat{x}_k \phi)(x) = x_k \phi(x) is the pointwise multiplication by the kk-th coordinate.

theorem

Antisymmetry of the Angular Momentum Operator Lij=−LjiL_{ij} = -L_{ji}

For any dimension dd and indices i,j∈{0,1,…,d−1}i, j \in \{0, 1, \dots, d-1\}, the components of the angular momentum operator LijL_{ij} acting on the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) satisfy the antisymmetry relation: Lij=−Lji L_{ij} = -L_{ji} where the operator is defined by Lij=x^ip^j−x^jp^iL_{ij} = \hat{x}_i \hat{p}_j - \hat{x}_j \hat{p}_i.

theorem

Lii=0L_{ii} = 0 for Angular Momentum Operator components

For any dimension dd and any index i∈{0,1,…,d−1}i \in \{0, 1, \dots, d-1\}, the iiii-th component of the angular momentum operator, defined as Lij=x^ip^j−x^jp^iL_{ij} = \hat{x}_i \hat{p}_j - \hat{x}_j \hat{p}_i, vanishes. That is, Lii=0L_{ii} = 0.

definition

Notation for L2\mathbf{L}^2

The notation L2\mathbf{L}^2 represents the squared angular momentum operator. As defined in the context of quantum mechanics on a dd-dimensional space, it acts on the space of Schwartz functions S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) according to the formula L2=12∑i,jLij∘Lij\mathbf{L}^2 = \frac{1}{2} \sum_{i,j} \mathbf{L}_{ij} \circ \mathbf{L}_{ij}, where Lij\mathbf{L}_{ij} are the components of the angular momentum operator.

theorem

The domain of LijL_{ij} is the Schwartz space

For any dimension dd and indices i,j∈{0,…,d−1}i, j \in \{0, \dots, d-1\}, the domain of the ijij-th component of the angular momentum operator LijL_{ij} is the Schwartz space S(Space d,C)\mathcal{S}(\text{Space } d, \mathbb{C}), regarded as a submodule of the Hilbert space L2(Space d,C)L^2(\text{Space } d, \mathbb{C}).

theorem

The action of LijL_{ij} on the Schwartz subspace of L2L^2 equals its action on the Schwartz space

For any dimension dd and indices i,j∈{0,…,d−1}i, j \in \{0, \dots, d-1\}, let ψ\psi be a wave function belonging to the Schwartz submodule of the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}). The ijij-th component of the angular momentum operator Lij=xipj−xjpiL_{ij} = x_i p_j - x_j p_i applied to ψ\psi is equal almost everywhere (with respect to the volume measure) to the result of applying the operator LijL_{ij} (defined as a continuous linear map on the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C})) to the corresponding function in the Schwartz space.

theorem

The Angular Momentum Operator LijL_{ij} Maps the Schwartz Space to Itself

For any dimension dd and indices i,j∈{0,…,d−1}i, j \in \{0, \dots, d-1\}, if a wave function ψ\psi belongs to the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}), then the result of applying the ijij-th component of the angular momentum operator Lij=xipj−xjpiL_{ij} = x_i p_j - x_j p_i to ψ\psi is also an element of the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}).

theorem

The Angular Momentum Operator LijL_{ij} has a Dense Domain in L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C})

For any dimension dd and indices i,j∈{0,…,d−1}i, j \in \{0, \dots, d-1\}, the ijij-th component of the angular momentum operator Lij=xipj−xjpiL_{ij} = x_i p_j - x_j p_i, acting on the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}), has a dense domain in the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}).

theorem

Lij=p^jx^i−p^ix^jL_{ij} = \hat{p}_j \hat{x}_i - \hat{p}_i \hat{x}_j

For any dimension dd and indices i,j∈{0,…,d−1}i, j \in \{0, \dots, d-1\}, the ijij-th component of the angular momentum operator LijL_{ij} on the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) can be expressed by reversing the order of the position and momentum operators: Lij=p^jx^i−p^ix^j L_{ij} = \hat{p}_j \hat{x}_i - \hat{p}_i \hat{x}_j where x^i\hat{x}_i is the ii-th position operator (multiplication by the ii-th coordinate) and p^j\hat{p}_j is the jj-th momentum operator (acting as −iℏ∂j-i\hbar \partial_j). This identity confirms that the definition Lij=x^ip^j−x^jp^iL_{ij} = \hat{x}_i \hat{p}_j - \hat{x}_j \hat{p}_i is invariant under the reversal of the operator ordering.

theorem

The Angular Momentum Operator Components LijL_{ij} are Symmetric

For any dimension dd and indices i,j∈{0,…,d−1}i, j \in \{0, \dots, d-1\}, the ijij-th component of the angular momentum operator Lij=xipj−xjpiL_{ij} = x_i p_j - x_j p_i is a symmetric operator on the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}). Specifically, for any two wavefunctions ψ,ϕ\psi, \phi in the Schwartz domain, the L2L^2 inner product satisfies: ⟨Lijψ,ϕ⟩=⟨ψ,Lijϕ⟩\langle L_{ij} \psi, \phi \rangle = \langle \psi, L_{ij} \phi \rangle where xix_i and pjp_j are the position and momentum operators, respectively.

theorem

LijL_{ij} is densely defined and closable

For any dimension dd and indices i,j∈{0,…,d−1}i, j \in \{0, \dots, d-1\}, the ijij-th component of the angular momentum operator Lij=xipj−xjpiL_{ij} = x_i p_j - x_j p_i, acting on the domain of Schwartz functions S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) within the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}), is densely defined and closable.

theorem

Symmetry of LijL_{ij} with respect to the L2L^2 inner product

For a given dimension dd and indices i,j∈{0,1,…,d−1}i, j \in \{0, 1, \dots, d-1\}, let LijL_{ij} be the ijij-th component of the angular momentum operator acting on the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}). For any two functions f,g∈S(Rd,C)f, g \in \mathcal{S}(\mathbb{R}^d, \mathbb{C}), the L2L^2 inner product satisfies the symmetry identity: ⟨Lijf,g⟩L2=⟨f,Lijg⟩L2 \langle L_{ij} f, g \rangle_{L^2} = \langle f, L_{ij} g \rangle_{L^2} where the Schwartz functions are treated as elements of the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}) via the standard inclusion.

definition

Angular momentum squared operator L2\mathbf{L}^2 on L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C})

The angular momentum squared operator L2\mathbf{L}^2 is a linear operator on the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}) with the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) as its domain. It is defined by transporting the operator L2=12∑i,j=0d−1Lij∘Lij\mathbf{L}^2 = \frac{1}{2} \sum_{i,j=0}^{d-1} L_{ij} \circ L_{ij} (where LijL_{ij} are the components of the angular momentum operator) from the Schwartz space to the Hilbert space.

definition

Notation for the angular momentum squared operator L2\mathbf{L}^2

This definition introduces the notation L2\mathbf{L}^2 for the angular momentum squared operator. This operator acts on the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) and is defined by the sum L2=12∑i,jLij∘Lij\mathbf{L}^2 = \frac{1}{2} \sum_{i,j} \mathbf{L}_{ij} \circ \mathbf{L}_{ij}, where Lij\mathbf{L}_{ij} are the components of the angular momentum operator.

theorem

Domain of L2=S(Rd,C)\mathbf{L}^2 = \mathcal{S}(\mathbb{R}^d, \mathbb{C})

The domain of the dd-dimensional angular momentum squared operator L2\mathbf{L}^2 is the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}).

theorem

Action of the angular momentum squared operator L2\mathbf{L}^2 on the Schwartz submodule of L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C})

Let S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) be the Schwartz space and SL2⊂L2(Rd,C)\mathcal{S}_{L^2} \subset L^2(\mathbb{R}^d, \mathbb{C}) be the corresponding submodule of the Hilbert space of square-integrable functions. For any element ψ∈SL2\psi \in \mathcal{S}_{L^2}, the action of the angular momentum squared operator L2\mathbf{L}^2 on the Hilbert space is given by: L2ψ=Φ(LS2(Φ−1(ψ)))\mathbf{L}^2 \psi = \Phi(\mathbf{L}^2_{\mathcal{S}}(\Phi^{-1}(\psi))) where Φ:S(Rd,C)→SL2\Phi: \mathcal{S}(\mathbb{R}^d, \mathbb{C}) \to \mathcal{S}_{L^2} is the canonical linear isomorphism between the Schwartz space and its image in the Hilbert space, and LS2\mathbf{L}^2_{\mathcal{S}} is the angular momentum squared operator defined on the Schwartz space.

theorem

The L2L^2 angular momentum squared operator L2\mathbf{L}^2 equals the Schwartz space operator L2\mathbf{L}^2 almost everywhere.

For any dimension dd, let ψ\psi be an element of the Schwartz submodule of the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}). The application of the angular momentum squared operator L2\mathbf{L}^2 (as defined on the Hilbert space) to ψ\psi is equal almost everywhere (with respect to the Lebesgue volume measure) to the result of applying the Schwartz-space angular momentum squared operator to the Schwartz function corresponding to ψ\psi.

theorem

The angular momentum squared operator L2\mathbf{L}^2 maps the Schwartz space into itself

For any function ψ\psi in the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) (viewed as a submodule of the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C})), applying the angular momentum squared operator L2\mathbf{L}^2 results in a function that is also in the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}).

theorem

L2=12∑i,jLij2\mathbf{L}^2 = \frac{1}{2} \sum_{i,j} L_{ij}^2 on the Schwartz space

For any wave function ψ\psi in the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}), the angular momentum squared operator L2\mathbf{L}^2 acts as the sum of the squares of the components LijL_{ij}: L2ψ=12∑i=0d−1∑j=0d−1Lij(Lijψ),\mathbf{L}^2 \psi = \frac{1}{2} \sum_{i=0}^{d-1} \sum_{j=0}^{d-1} L_{ij}(L_{ij} \psi), where Lij=xipj−xjpiL_{ij} = x_i p_j - x_j p_i is the ijij-th component of the angular momentum operator. The composition Lij(Lijψ)L_{ij}(L_{ij} \psi) is well-defined because each LijL_{ij} maps the Schwartz space to itself.

theorem

The Domain of the Angular Momentum Squared Operator L2\mathbf{L}^2 is Dense in L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C})

The domain of the angular momentum squared operator L2\mathbf{L}^2 is dense in the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}). Here, L2\mathbf{L}^2 is defined as a linear operator with the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) as its domain, and the dense property indicates that S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) is a dense subspace of the space of square-integrable functions L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}).

theorem

Symmetry of the angular momentum squared operator L2\mathbf{L}^2 with respect to the L2L^2 inner product

For any two functions f,gf, g in the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}), the angular momentum squared operator L2\mathbf{L}^2 is symmetric with respect to the L2L^2 inner product. That is, ⟨L2f,g⟩=⟨f,L2g⟩,\langle \mathbf{L}^2 f, g \rangle = \langle f, \mathbf{L}^2 g \rangle, where ⟨⋅,⋅⟩\langle \cdot, \cdot \rangle denotes the inner product in the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}). This symmetry is obtained by shifting each component of the operator across the inner product.

theorem

Symmetry of the Angular Momentum Squared Operator L2\mathbf{L}^2

The angular momentum squared operator L2\mathbf{L}^2 on the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}), with the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) as its domain, is a symmetric operator. This means that for any two functions f,gf, g in the Schwartz space, the L2L^2 inner product satisfies ⟨L2f,g⟩=⟨f,L2g⟩\langle \mathbf{L}^2 f, g \rangle = \langle f, \mathbf{L}^2 g \rangle.

theorem

The angular momentum squared operator L2\mathbf{L}^2 is densely defined and closable

The angular momentum squared operator L2\mathbf{L}^2 on the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}), with the Schwartz space S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) as its domain, is densely defined and closable.