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Physlib.QuantumMechanics.OneDimension.HarmonicOscillator.TISE

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definition

The nn-th energy eigenvalue of a harmonic oscillator En=(n+1/2)ωE_n = (n + 1/2)\hbar\omega

#eigenValue

For a one-dimensional quantum harmonic oscillator with angular frequency ω\omega, the nn-th energy eigenvalue EnE_n corresponding to the quantum number nNn \in \mathbb{N} is defined as: En=(n+12)ωE_n = \left(n + \frac{1}{2}\right) \hbar \omega where \hbar is the reduced Planck constant.

theorem

ψ0(x)=xξ2ψ0(x)\psi_0'(x) = -\frac{x}{\xi^2} \psi_0(x)

#deriv_eigenfunction_zero

Let ψ0\psi_0 be the ground state eigenfunction (the eigenfunction with index n=0n=0) of a one-dimensional quantum harmonic oscillator with characteristic length ξ\xi. Its derivative ψ0\psi_0' satisfies ψ0(x)=xξ2ψ0(x).\psi_0'(x) = -\frac{x}{\xi^2} \psi_0(x).

theorem

ψ0(x)=22ξψ1(x)\psi_0'(x) = -\frac{\sqrt{2}}{2\xi} \psi_1(x)

#deriv_eigenfunction_zero'

Let ψn\psi_n be the nn-th eigenfunction of a one-dimensional quantum harmonic oscillator with characteristic length ξ\xi. The derivative of the ground state eigenfunction ψ0\psi_0 is proportional to the first excited state eigenfunction ψ1\psi_1 according to the relation: ψ0(x)=22ξψ1(x).\psi_0'(x) = -\frac{\sqrt{2}}{2\xi} \psi_1(x).

theorem

ddxHn(x/ξ)=2nξHn1(x/ξ)\frac{d}{dx} H_n(x/\xi) = \frac{2n}{\xi} H_{n-1}(x/\xi)

#deriv_physHermite_characteristic_length

For any natural number nn, the derivative with respect to xx of the nn-th physicist's Hermite polynomial HnH_n evaluated at x/ξx/\xi is given by ddxHn(xξ)=2nξHn1(xξ),\frac{d}{dx} H_n\left(\frac{x}{\xi}\right) = \frac{2n}{\xi} H_{n-1}\left(\frac{x}{\xi}\right), where ξ\xi is the characteristic length of the quantum harmonic oscillator.

theorem

Derivative of the (n+1)(n+1)-th QHO eigenfunction ψn+1\psi_{n+1}

#deriv_eigenfunction_succ

Let ψn\psi_n be the nn-th eigenfunction of a one-dimensional quantum harmonic oscillator with characteristic length ξ\xi. For any natural number nn, the derivative of the (n+1)(n+1)-th eigenfunction ψn+1\psi_{n+1} is given by ψn+1(x)=1ξ2n+1(n+1)!(2(n+1)Hn(xξ)xξHn+1(xξ))ψ0(x),\psi_{n+1}'(x) = \frac{1}{\xi \sqrt{2^{n+1} (n+1)!}} \left( 2(n+1) H_n\left(\frac{x}{\xi}\right) - \frac{x}{\xi} H_{n+1}\left(\frac{x}{\xi}\right) \right) \psi_0(x), where HkH_k denotes the kk-th physicist's Hermite polynomial and ψ0\psi_0 is the ground state eigenfunction.

theorem

ψ0(x)=1ξ2(1x2ξ2)ψ0(x)\psi_0''(x) = -\frac{1}{\xi^2} \left(1 - \frac{x^2}{\xi^2}\right) \psi_0(x)

#deriv_deriv_eigenfunction_zero

Let ψ0(x)\psi_0(x) be the ground state eigenfunction (the eigenfunction with index n=0n=0) of a one-dimensional quantum harmonic oscillator with characteristic length ξ\xi. For any xRx \in \mathbb{R}, the second derivative of the eigenfunction, denoted ψ0(x)\psi_0''(x), is given by: ψ0(x)=1ξ2(1x2ξ2)ψ0(x).\psi_0''(x) = -\frac{1}{\xi^2} \left(1 - \frac{x^2}{\xi^2}\right) \psi_0(x).

theorem

Second derivative of the (n+1)(n+1)-th QHO eigenfunction ψn+1\psi_{n+1}

#deriv_deriv_eigenfunction_succ

Let ψn\psi_n be the nn-th eigenfunction of a one-dimensional quantum harmonic oscillator with characteristic length ξ\xi. For any natural number nn and any position xRx \in \mathbb{R}, the second derivative of the (n+1)(n+1)-th eigenfunction ψn+1\psi_{n+1} is given by ψn+1(x)=1ξ2n+1(n+1)![2(n+1)ddxHn(xξ)4(n+1)xξ2Hn(xξ)1ξ(1x2ξ2)Hn+1(xξ)]ψ0(x),\psi_{n+1}''(x) = \frac{1}{\xi \sqrt{2^{n+1} (n+1)!}} \left[ 2(n+1) \frac{d}{dx} H_n\left(\frac{x}{\xi}\right) - \frac{4(n+1)x}{\xi^2} H_n\left(\frac{x}{\xi}\right) - \frac{1}{\xi} \left( 1 - \frac{x^2}{\xi^2} \right) H_{n+1}\left(\frac{x}{\xi}\right) \right] \psi_0(x), where HkH_k denotes the kk-th physicist's Hermite polynomial and ψ0\psi_0 is the ground state eigenfunction.

theorem

ψn(x)=1ξ2(2n+1x2ξ2)ψn(x)\psi_n''(x) = -\frac{1}{\xi^2} \left( 2n + 1 - \frac{x^2}{\xi^2} \right) \psi_n(x)

#deriv_deriv_eigenfunction

Let ψn\psi_n be the nn-th eigenfunction of a one-dimensional quantum harmonic oscillator with characteristic length ξ\xi. For any natural number nn and any position xRx \in \mathbb{R}, the second derivative of the eigenfunction ψn\psi_n with respect to xx is given by ψn(x)=1ξ2(2n+1x2ξ2)ψn(x).\psi_n''(x) = -\frac{1}{\xi^2} \left( 2n + 1 - \frac{x^2}{\xi^2} \right) \psi_n(x).

theorem

H^ψn=Enψn\hat{H} \psi_n = E_n \psi_n for the Harmonic Oscillator

#schrodingerOperator_eigenfunction

Let QQ be a one-dimensional quantum harmonic oscillator. For any natural number nNn \in \mathbb{N} and any position xRx \in \mathbb{R}, the nn-th eigenfunction ψn\psi_n satisfies the time-independent Schrödinger equation: H^ψn(x)=Enψn(x)\hat{H} \psi_n(x) = E_n \psi_n(x) where H^\hat{H} is the Schrödinger operator (Hamiltonian) of the oscillator and EnE_n is the nn-th energy eigenvalue, defined as En=(n+1/2)ωE_n = (n + 1/2)\hbar\omega.