Physlib.QuantumMechanics.HarmonicOscillator.Eigenstates
Energy eigenstates of the quantum harmonic oscillator
i. Overview
The quantum harmonic oscillator in `d` dimensions is exactly solvable - the energy eigenvalues and eigenfunction can be computed analytically.
The ground-state wavefunction is a normalized Gaussian with covariance controlled by the harmonic oscillator's characteristic lengths. A general state is then obtained by acting on the ground state with the raising operators and is labelled by `d` integer quantum numbers. Their wavefunctions are given by products of (physicist's) Hermite polynomials multiplying the ground-state Gaussian.
When the potential is isotropic another description of the energy eigenstates is possible; energy eigenspaces carry SO(d) representations and eigenfunctions can be written in terms of hyperspherical harmonics. In such cases the energies only depend on the radial quantum number.
ii. Key results
iii. Table of contents
- A. Cartesian basis - A.1. Energy eigenvalues - A.2. Eigenfunctions - A.3. Eigenstates
iv. References
A. Cartesian basis
A.1. Energy eigenvalues
A.2. Eigenfunctions
A.3. Eigenstates
11 declarations
Energy eigenvalue of the quantum harmonic oscillator
For a quantum harmonic oscillator in dimensions, the energy eigenvalue associated with a vector of quantum numbers is given by the sum , where is the angular frequency of the -th dimension, is the corresponding non-negative integer quantum number, and is the reduced Planck constant.
Energy Eigenvalue Formula for the Quantum Harmonic Oscillator
For a quantum harmonic oscillator in dimensions with angular frequencies for each dimension , the energy eigenvalue associated with a vector of non-negative integer quantum numbers is given by the sum where is the reduced Planck constant.
The energy eigenvalue is strictly monotonic in the quantum numbers
For a quantum harmonic oscillator, the energy eigenvalue function , which maps a vector of quantum numbers to its corresponding energy , is strictly monotonic. That is, if (meaning for all and for at least one ), then .
Normalization constant for the -th component of a quantum harmonic oscillator eigenfunction
For a -dimensional quantum harmonic oscillator and a given set of quantum numbers , the normalization coefficient for the -th dimension is defined as: where is the quantum number associated with the -th dimension and is the characteristic length of the oscillator in that dimension.
The normalization coefficient for the -th component of a quantum harmonic oscillator eigenfunction is
For a -dimensional quantum harmonic oscillator and a given set of quantum numbers , the normalization coefficient for the -th dimension is given by: where is the quantum number associated with the -th dimension and is the characteristic length of the oscillator in that dimension.
Energy eigenfunction of the -dimensional quantum harmonic oscillator
For a quantum harmonic oscillator in dimensions with characteristic lengths , and given a set of integer quantum numbers , the energy eigenfunction is a Schwartz function in defined by the product: where are the Cartesian coordinates and denotes the -th physicist's Hermite polynomial.
The energy eigenfunction is a product of Hermite polynomials and a scaled Gaussian
For a -dimensional quantum harmonic oscillator with characteristic lengths and a set of quantum numbers , the energy eigenfunction is defined by multiplying the standard Gaussian by the product of normalization coefficients and physicist's Hermite polynomials , and then pre-composing with the scaling transformation . Explicitly, the eigenfunction is given by: where the normalization constant for the -th component is .
Value of the Energy Eigenfunction for a -dimensional Quantum Harmonic Oscillator
For a quantum harmonic oscillator in dimensions with characteristic lengths , and given a vector of integer quantum numbers , the value of the energy eigenfunction at a position is given by the product: where are the normalization coefficients (`eigenCoeff`), are the -th physicist's Hermite polynomials, and are the characteristic lengths in each dimension.
Energy eigenstate of a -dimensional harmonic oscillator in the Hilbert space
For a quantum harmonic oscillator in dimensions and a vector of quantum numbers , the energy eigenstate is the element of the Schwartz submodule of the Hilbert space corresponding to the energy eigenfunction . It is defined by mapping the Schwartz function into the Hilbert space via the canonical linear isomorphism.
The energy eigenstate equals the image of the eigenfunction under the Schwartz-Hilbert isomorphism
For a -dimensional quantum harmonic oscillator and a vector of quantum numbers , the energy eigenstate in the Hilbert space is equal to the image of the energy eigenfunction under the canonical linear isomorphism between the Schwartz space and its corresponding subspace in the Hilbert space .
Orthonormality of Energy Eigenstates
For a -dimensional quantum harmonic oscillator , the inner product of two energy eigenstates with multi-indices of quantum numbers in the Hilbert space is equal to the Kronecker delta . That is, where is if and otherwise.
