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Physlib.QuantumMechanics.HarmonicOscillator.Eigenstates

Energy eigenstates of the quantum harmonic oscillator

i. Overview

The quantum harmonic oscillator in `d` dimensions is exactly solvable - the energy eigenvalues and eigenfunction can be computed analytically.

The ground-state wavefunction is a normalized Gaussian with covariance controlled by the harmonic oscillator's characteristic lengths. A general state is then obtained by acting on the ground state with the raising operators and is labelled by `d` integer quantum numbers. Their wavefunctions are given by products of (physicist's) Hermite polynomials multiplying the ground-state Gaussian.

When the potential is isotropic another description of the energy eigenstates is possible; energy eigenspaces carry SO(d) representations and eigenfunctions can be written in terms of hyperspherical harmonics. In such cases the energies only depend on the radial quantum number.

ii. Key results

iii. Table of contents

- A. Cartesian basis - A.1. Energy eigenvalues - A.2. Eigenfunctions - A.3. Eigenstates

iv. References

A. Cartesian basis

A.1. Energy eigenvalues

A.2. Eigenfunctions

A.3. Eigenstates

11 declarations

definition

Energy eigenvalue En=iωi(ni+12)E_n = \sum_i \hbar \omega_i (n_i + \frac{1}{2}) of the quantum harmonic oscillator

For a quantum harmonic oscillator in dd dimensions, the energy eigenvalue associated with a vector of quantum numbers nn is given by the sum En=iωi(ni+12)E_n = \sum_i \hbar \omega_i (n_i + \frac{1}{2}), where ωi\omega_i is the angular frequency of the ii-th dimension, nin_i is the corresponding non-negative integer quantum number, and \hbar is the reduced Planck constant.

theorem

Energy Eigenvalue Formula En=iωi(ni+12)E_n = \sum_i \hbar \omega_i (n_i + \frac{1}{2}) for the Quantum Harmonic Oscillator

For a quantum harmonic oscillator in dd dimensions with angular frequencies ωi\omega_i for each dimension ii, the energy eigenvalue EnE_n associated with a vector of non-negative integer quantum numbers n=(n1,n2,,nd)n = (n_1, n_2, \dots, n_d) is given by the sum En=iωi(ni+12)E_n = \sum_{i} \hbar \omega_i \left(n_i + \frac{1}{2}\right) where \hbar is the reduced Planck constant.

theorem

The energy eigenvalue EnE_n is strictly monotonic in the quantum numbers nn

For a quantum harmonic oscillator, the energy eigenvalue function EnE_n, which maps a vector of quantum numbers nNdn \in \mathbb{N}^d to its corresponding energy En=iωi(ni+12)E_n = \sum_i \hbar \omega_i (n_i + \frac{1}{2}), is strictly monotonic. That is, if n<mn < m (meaning nimin_i \leq m_i for all ii and nj<mjn_j < m_j for at least one jj), then En<EmE_n < E_m.

definition

Normalization constant for the ii-th component of a quantum harmonic oscillator eigenfunction

For a dd-dimensional quantum harmonic oscillator QQ and a given set of quantum numbers n=(n1,,nd)n = (n_1, \dots, n_d), the normalization coefficient for the ii-th dimension is defined as: 12nini!πξi \frac{1}{\sqrt{2^{n_i} n_i! \sqrt{\pi} \xi_i}} where nin_i is the quantum number associated with the ii-th dimension and ξi\xi_i is the characteristic length of the oscillator in that dimension.

theorem

The normalization coefficient for the ii-th component of a quantum harmonic oscillator eigenfunction is 12nini!πξi\frac{1}{\sqrt{2^{n_i} n_i! \sqrt{\pi} \xi_i}}

For a dd-dimensional quantum harmonic oscillator QQ and a given set of quantum numbers n=(n1,,nd)n = (n_1, \dots, n_d), the normalization coefficient for the ii-th dimension is given by: eigenCoeff(n,i)=12nini!πξi \text{eigenCoeff}(n, i) = \frac{1}{\sqrt{2^{n_i} n_i! \sqrt{\pi} \xi_i}} where nin_i is the quantum number associated with the ii-th dimension and ξi\xi_i is the characteristic length of the oscillator in that dimension.

definition

Energy eigenfunction ψn\psi_n of the dd-dimensional quantum harmonic oscillator

For a quantum harmonic oscillator QQ in dd dimensions with characteristic lengths ξ=(ξ1,,ξd)\xi = (\xi_1, \dots, \xi_d), and given a set of integer quantum numbers n=(n1,,nd)Ndn = (n_1, \dots, n_d) \in \mathbb{N}^d, the energy eigenfunction ψn\psi_n is a Schwartz function in S(Rd,C)\mathcal{S}(\mathbb{R}^d, \mathbb{C}) defined by the product: ψn(x)=i=1d12nini!πξiHni(xiξi)exp(12(xiξi)2)\psi_n(x) = \prod_{i=1}^d \frac{1}{\sqrt{2^{n_i} n_i! \sqrt{\pi} \xi_i}} H_{n_i}\left(\frac{x_i}{\xi_i}\right) \exp\left(-\frac{1}{2} \left(\frac{x_i}{\xi_i}\right)^2\right) where x=(x1,,xd)Rdx = (x_1, \dots, x_d) \in \mathbb{R}^d are the Cartesian coordinates and HniH_{n_i} denotes the nin_i-th physicist's Hermite polynomial.

theorem

The energy eigenfunction ψn\psi_n is a product of Hermite polynomials and a scaled Gaussian

For a dd-dimensional quantum harmonic oscillator QQ with characteristic lengths ξ=(ξ1,,ξd)\xi = (\xi_1, \dots, \xi_d) and a set of quantum numbers n=(n1,,nd)n = (n_1, \dots, n_d), the energy eigenfunction ψn\psi_n is defined by multiplying the standard Gaussian g(x)=exp(12x2)g(x) = \exp\left(-\frac{1}{2} \|x\|^2\right) by the product of normalization coefficients and physicist's Hermite polynomials HniH_{n_i}, and then pre-composing with the scaling transformation x(x1/ξ1,,xd/ξd)x \mapsto (x_1/\xi_1, \dots, x_d/\xi_d). Explicitly, the eigenfunction is given by: ψn(x)=i=1deigenCoeff(n,i)Hni(xiξi)exp(12(xiξi)2)\psi_n(x) = \prod_{i=1}^d \text{eigenCoeff}(n, i) H_{n_i}\left(\frac{x_i}{\xi_i}\right) \exp\left(-\frac{1}{2} \left(\frac{x_i}{\xi_i}\right)^2\right) where the normalization constant for the ii-th component is eigenCoeff(n,i)=12nini!πξi\text{eigenCoeff}(n, i) = \frac{1}{\sqrt{2^{n_i} n_i! \sqrt{\pi} \xi_i}}.

theorem

Value of the Energy Eigenfunction ψn(x)\psi_n(x) for a dd-dimensional Quantum Harmonic Oscillator

For a quantum harmonic oscillator QQ in dd dimensions with characteristic lengths ξ=(ξ1,,ξd)\xi = (\xi_1, \dots, \xi_d), and given a vector of integer quantum numbers n=(n1,,nd)Ndn = (n_1, \dots, n_d) \in \mathbb{N}^d, the value of the energy eigenfunction ψn\psi_n at a position x=(x1,,xd)Rdx = (x_1, \dots, x_d) \in \mathbb{R}^d is given by the product: ψn(x)=i=1dCn,iHni(xiξi)exp(12(xiξi)2)\psi_n(x) = \prod_{i=1}^d C_{n,i} H_{n_i}\left(\frac{x_i}{\xi_i}\right) \exp\left(-\frac{1}{2} \left(\frac{x_i}{\xi_i}\right)^2\right) where Cn,iC_{n,i} are the normalization coefficients (`eigenCoeff`), HniH_{n_i} are the nin_i-th physicist's Hermite polynomials, and ξi\xi_i are the characteristic lengths in each dimension.

definition

Energy eigenstate of a dd-dimensional harmonic oscillator in the Hilbert space

For a quantum harmonic oscillator QQ in dd dimensions and a vector of quantum numbers n=(n1,,nd)Ndn = (n_1, \dots, n_d) \in \mathbb{N}^d, the energy eigenstate is the element of the Schwartz submodule of the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}) corresponding to the energy eigenfunction ψn\psi_n. It is defined by mapping the Schwartz function ψnS(Rd,C)\psi_n \in \mathcal{S}(\mathbb{R}^d, \mathbb{C}) into the Hilbert space via the canonical linear isomorphism.

theorem

The energy eigenstate n|n\rangle equals the image of the eigenfunction ψn\psi_n under the Schwartz-Hilbert isomorphism

For a dd-dimensional quantum harmonic oscillator QQ and a vector of quantum numbers n=(n1,,nd)Ndn = (n_1, \dots, n_d) \in \mathbb{N}^d, the energy eigenstate n|n\rangle in the Hilbert space is equal to the image of the energy eigenfunction ψnS(Rd,C)\psi_n \in \mathcal{S}(\mathbb{R}^d, \mathbb{C}) under the canonical linear isomorphism between the Schwartz space and its corresponding subspace in the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}).

theorem

Orthonormality of Energy Eigenstates ψn,ψn=δnn\langle \psi_n, \psi_{n'} \rangle = \delta_{nn'}

For a dd-dimensional quantum harmonic oscillator QQ, the inner product of two energy eigenstates with multi-indices of quantum numbers n,nNdn, n' \in \mathbb{N}^d in the Hilbert space L2(Rd,C)L^2(\mathbb{R}^d, \mathbb{C}) is equal to the Kronecker delta δn,n\delta_{n, n'}. That is, ψn,ψn=δn,n\langle \psi_n, \psi_{n'} \rangle = \delta_{n, n'} where δn,n\delta_{n, n'} is 11 if n=nn = n' and 00 otherwise.