Physlib

Physlib.QuantumMechanics.FreeParticle.Basic

The free particle on `Space d`

i. Overview

The free quantum particle is one of the simplest quantum systems. States for a particle of mass `m` are elements of `SpaceDHilbertSpace d` and evolve according to the Hamiltonian `p²/2m` with no potential.

ii. Key results

iii. Table of contents

  • A. Basic properties
  • B. Hilbert space
  • C. Hamiltonian
  • D. As a quantum system

iv. References

A. Basic properties

B. Hilbert space

C. Hamiltonian

D. As a quantum system

7 declarations

theorem

The mass of a free particle is positive (m>0m > 0)

For a free quantum particle QQ, the mass mm is strictly positive, i.e., 0<m0 < m.

theorem

The mass mm of a free particle is non-negative (0m0 \le m)

For a free quantum particle QQ, its mass mm is non-negative, satisfying the inequality 0m0 \le m.

theorem

The mass mm of a free particle is non-zero (m0m \neq 0)

For a free quantum particle QQ in dd dimensions, its mass mm is non-zero (m0m \neq 0).

abbrev

Hilbert space of a free particle in dd dimensions

For a free particle in dd dimensions, the associated Hilbert space is defined as L2(Space d,C)L^2(\text{Space } d, \mathbb{C}), which is the space of square-integrable complex-valued functions on the dd-dimensional space Space d\text{Space } d.

definition

Free particle Hamiltonian H=p22mH = \frac{\mathbf{p}^2}{2m}

For a free particle QQ of mass mm in dd dimensions, the Hamiltonian HH is defined as a partial linear map on the Hilbert space L2(Space d,C)L^2(\text{Space } d, \mathbb{C}) given by H=12mp2 H = \frac{1}{2m} \mathbf{p}^2 where p2\mathbf{p}^2 is the momentum-squared operator (proportional to the Laplacian). This operator represents the kinetic energy of the particle in the absence of a potential.

definition

The Hamiltonian of a free particle is essentially self-adjoint

The Hamiltonian operator HH for a free particle in dd dimensions is essentially self-adjoint on its domain in the Hilbert space.

definition

Free particle as a quantum system

The free particle in dd dimensions is represented as a quantum system. This structure packages the Hilbert space H\mathcal{H} (typically L2(Rd)L^2(\mathbb{R}^d)) and the self-adjoint Hamiltonian operator H=p22mH = \frac{\mathbf{p}^2}{2m} into a single quantum system object, where p\mathbf{p} is the momentum operator and mm is the mass of the particle.